Monovalent Copper Ligands (MCL-Series)

Thermodynamic Data

Ligand E (V vs. SHE) pKa logKCu(II)L logKCu(I)L logK'Cu(I)L pCu
MCL-1 0.716(1) 7.00(2) 6.42(2) 16.33(2) 16.0 16.9
MCL-2 n/a 8.98(1) - 13.08(13) 11.0 11.9
MCL-3 0.729(3) n/a 3.47(4) 13.80(3) 13.8 14.8

Calculate the Apparent Affinity (I = 0.1)

Structures of Cu(I) Complexes

MCL-1   (cif file)
MCL-2   (cif file)
trMCL-3   (cif file)